Proceedings of the Technical Session of Institute of Physics, Sri Lanka 16 (2000) 1-13
Absolute PulseAmplitudes of Isolated Cloud Flashes
Chandima Gomes and Vernon Cooray
Institute of high Voltage Research,
Uppsala University, Sweden
Sixty isolated cloud flashes pertinent to two Swedish thunder storms of which 30 flasheswere distance located with time-to-thunder measurements, have been analysed. The main objectives of this analysis were to estimate the temporal pulse characteristics, to determine the absolute pulse amplitudes and to investigate the time of occurrence of the most active region of the pulse train. The long duration of the cloud flashes, mainly distinguish them from other known pulse trains. In pulse characteristics, they are considerably different from the preliminary breakdown pulse trains of negative return strokes and somewhat similar to those pulse trains of positive return strokes,observed in Sweden. There are two types of pulses, multiple peaked pulses, with less pronounced positive overshoot, and single peaked pulses, with pronounced positive overshoot. The mean pulse characteristics, width of the initial half cycle, width of the second half cycle, full width of the pulses and the pulse separation, have values of 21 ms, 23 ms, 43 ms, and 147 ms, respectively. The mean pulse train duration is 55 ms. The pulse amplitude, during the first 10 ms, is 3 times greater than that ofpulses occur, during the following 30 ms. The pulse occurrence density, during the first 10 ms, is about 4 times greater than that of the following 30 ms. The emission of the 3 MHz radiation starts with the onset of the pulse train and the strongest emission is observed during the first 10 ms. The mean amplitude of the largest pulse, normalised to 15 km, is 20.3 V/m, thus, similar to that of subsequent strokes.
Back to content pageProceedings of the Technical Session of Institute of Physics, Sri Lanka 16 (2000) 14-33
Lightning
Electromagnetic Environment
Chandima Gomes
Department of Physics, University of Colombo, Colombo 03,Sri
Lanka
Lightning current and electromagnetic field parameters are of prime importance in designing lightning protection devices and in many other physics and engineering applications. Several reviews on lightning currents in both natural and artificial lightning are published, however a review on lightning generated electromagnetic fields is not available in either local or international literature. This study provides a concise review on up-to-date information of the lightning generatedelectromagnetic fields measured at various distances. The discussion is mainly confined into the lightning return stroke fields. The fields due to both negative and positive return strokes are treated.
Another important aspect of lightning, discussed in this work, is the repetitive nature of the main discharge event, the return stroke. This includes the number of strokes per flash, the fraction of strokes with amplitudes greater than that of the first stroke, the inter-stroke interval etc. These parameters are significant in the withstanding ability and the long-term durability of the lightning protection devices.
Back to content pageProceedings of the Technical Session of Institute of Physics, Sri Lanka 16 (2000) 34-41
A
Study of LLPSystems and their Performance in Locating Lightning Ground
Flashes inSri Lanka (1998 - 1999)
D. U. J. Sonnadara for LLP group
Department of Physics,University of Colombo, Colombo 3
A study of the performance of wideband magnetic direction finding systems used in locating lightning ground flashes in Sri Lanka is presented. The studies carried out with these systems show that they are highly sensitive to the geometric placement with respect to each other as well as to the induced magnetic fields produce by the external objects in the vicinity of the antennas (site errors). The results of two studies carried out by placing two of these stations in the same vicinity of each other and also in two remote locations (Colombo6.90° N, 79.86° E and Ratnapura 6.68° N, 80.40° E)are presented.
Back to content pageProceedings of the Technical Session of Institute of Physics, Sri Lanka 16 (2000) 42-49
Preliminary
Results of Long-Term and Short-Term Rainfall Forecasting
H. K. W. I. Perera and D. U. J. Sonnadara
Department of Physics, University of Colombo
Possibility of using statistical methods for long-term and short-term rainfall forecasting was investigated. Daily rainfall data from 8 meteorology stations namely, Colombo, Ratnapura, Kandy, Galle, Hambanthota, Batticoloa, Anuradhapura and Trincomalee were utilised in this study. A time series model was used for long-term forecasting and a Markov Chainmodel was used for short-term forecasting. The preliminary results show that the time series model with exponential smoothing fitted the data best and seasonal variations can be predicted with this model from weekly and monthly averages. The Markov chain model, applied by considering only two states, wet or dry, was successful to the levelof 70% in predicting the status of a given day.
Back to content pageProceedings of the Technical Session of Institute of Physics, Sri Lanka 16 (2000) 50-62
Instrumental Developments in MALDI Time-of-Flight Mass
Spectrometry
C. K. G. Piyadasa1, P.
Håkansson2, T. R. Ariyaratne1
and D. F. Barofsky3
1 Departmentof Physics, University of Colombo,
Colombo 03, Sri Lanka., 2Division
of Ion Physics, Ångström Laboratory, Box
534,Uppsala, Sweden, 3
Department of Chemistry, Oregon State University, Corvallis, Oregon, USA.
Two new instrumental developments in matrix assisted laserdesorption/ionization (MALDI) time-of-flight (TOF) mass spectrometry is reviewed in this paper. In the first development, a high resolving power time-of-flight mass spectrometer was designed and constructed using two electrostatic mirrors, mounted symmetrically on the same optical axis facing each other. The ions produced in the MALDI source are pulsed into the region between the two mirrors using delayedextraction technique and trapped by successive reflections of opposite electric fields in the mirrors. The extension of the flight path due to the number of reflections is used to increase the mass resolving power in time-of-flight spectra. Mass resolutions of 55,000for an organic compound called substance-P was obtained for single laser shot spectra. The stability of protonated, sodiated and potassiated substance-P ions was also investigated.
In the second development, a electrostatic deflector has been designed and constructed that can be used in a reflecting MALDI time-of-flight mass spectrometer to select ions of a particular mass. The deflector consists of an interleaved set of parallel deflection electrodes. Thin metal ribbons instead of wires or plates are used for the deflection electrodes as a new concept. Properly timed reversing electric field was used for the operation of the device. With the newdeflector, a resolving power of ~ 5200 (FWHM) was obtained for anisotopomer of PEG 6000 (m/z ~ 6000) which is far better than that could be obtained from presently available commercial instruments.
Back to content pageProceedings of the Technical Session of Institute of Physics, Sri Lanka 16 (2000) 63-70
Fabrication and Characterisation of CuinS2/ZnSe/Metal
Structures for Solar Cell Applications
R. P. Wijesundera1,
N. P. Gunatunga1, W. Siripala1,K. D.
Jayasuriya1, S. R. D. Kalingamudali1,
K. T. L. De Silva2, J. K. D. S. Jayanetti2
1 Dept. of Physics, University
of Kelaniya, Kelaniya, 2 Dept. ofPhysics,
University of Colombo, Colombo
Thin film solar cellstructure of Ti/CuInS2/ZnSe/Metal was fabricated using simple electrochemical and sulphurisation techniques. Copper Indium Disulphide (CuInS2) thin films were prepared by sulphurisation of Cu-In alloy on Ti substrates. Films were characterised using X-ray diffraction (XRD), scanning electronmicroscopy (SEM), spectral response and I-V measurements. XRD measurements showed the characteristic peaks of CuInS2 and SEM showed that the crystallites are of the size 1-3 mm. ZnSe thin films were deposited on Ti/CuInS2 using electrodeposition technique. Ti/CuInS2/ZnSe/Metal structures were characterised using C-V, I-V and spectral response measurements. Light and dark I-V measurements revealed the photovoltaic activity of the structure while the C-V measurements confirmed the formation of the heterojunction. Spectral response showed that the photocarriers are generated by the absorption of light in the CuInS2layer.
Back to content pageProceedings of the Technical Session of Institute of Physics, Sri Lanka 16 (2000) 71-79
Effects
ofChromium Ion Doping on the Conduction Properties of TiO2
W. G. D. Dharmaratna and K. N. Cems
Departmentof Physics,
University of Ruhuna, Matara
The conduction properties of Cr-doped and undoped polycrystalline TiO2 powder are investigated. Rutile TiO2 is doped by using the method of high temperature (900 0C) diffusion. Cr2O3is used as the dopant precursor. ariation of electrical conductivity with temperature and dopant concentration is studied. Electronicconductivity of TiO2 increases by four orders of magnitudeand activation energy decreases by 60% as a result of doping. Both conductivity and activation energy depend on the dopant concentration. Highest conductivity and the lowest activation energy are obtained when the Cr2O3 concentration is about 5-6%.
Back to content pageProceedings of the Technical Session of Institute of Physics, Sri Lanka 16 (2000) 80-87
Fabrication of Clay Based
Ceramics for Engineering Applications
B. S. B. Karunaratne and S. T. Kumaratunga
Department of Physics,University of Peradeniya, Peradeniya
This paper describes some preliminary work concerned with the fabrication of clay based ceramics with suitable additives to obtain the properties required for engineering applications. In order to achieve this, the conventional porcelain body composition was modified by additions of oxides such as Y2O3, ZrO2, MgO, MnO,etc. to promote strong crystal structures and better bonding. Rectangular bar samples were prepared by slip casting as well as byuniaxial powder pressing under a pressure of 32 MPa and sintered at different temperatures close to 12000 C.x
The sintered samples were tested for their bend strength and wear resistance. The structural characterization of the samples was performed by X-ray diffraction (XRD). The bending tests revealed that bend strength varies significantly with different compositions and different maturing temperatures. Y2O3 and ZrO2added samples showed very encouraging results in relation to the bend strength. The bend strength of these two ceramics was about 30% higher than that for the conventional clay based ceramics.
The XRD analysis showed that the ZrO2 and Y2O3 doped samples contained more crystalline phases, thus justifying their strength. The high bending strength of ZrO2 added samples could also be attributed to the fact that those samples contained higher amounts of Mullite phases than their conventional counterparts. However, the wear resistance of these ceramics showed somewhat similar values. In conclusion it can be stated that this study indicates the possibility of developing cheap clay based ceramics as high technological ceramics by careful selection ofsuitable additives and sintering procedures.
Back to content pageProceedings of the Technical Session of Institute of Physics, Sri Lanka 16 (2000) 88-96
Application of Conducting Polymer (Polypyrrole) as an
Electrode in Li Rechargeable Batteries
K. P. Vidanapathirana, Kumudu
Perera and M. A. Careem
Department of Physics, University of peradeniya, Peradeniya
Li rechargeable cell was fabricated with a conducting polymer cathode. For that, conducting polymer polypyrrole (PPy) has been electropolymerized in the presence of large surfactant an ion dodecylbenzene sulfonate. A solid polymer electrolyte (SPE) was used as the electrolyte while Li was served as the anode. Cyclic voltammetry, continuos charge discharge tests and impedance measurements showed better cyclingcapacity and long cycling life.
Back to content pageProceedings of the Technical Session of Institute of Physics, Sri Lanka 16 (2000) 97-103
A
Polyacrylonitrile (PAN) Based Solid Polymer Electrolyte Complexedwith
Copper Trifluoromethanesulfonate (Cu(CF3So3)2)
Kumudu Perera, K. P. Vidanapathirana, M. A. K. L. Dissanayake,
P. W. S. K. Bandaranayake
Department of Physics, University of Peradeniya, Peradeniya
In this report, we present about a polymer electrolyte comprising of Polyacrylonitrile, ethylene carbonate, propylene carbonate and coppertrifluoromethanesulfonate. Preliminary studies have been performed to determine the composition having appropriate conductivities and mechanical properties. Impedance measurements and DC polarization tests have been done to calculate the activation energy and ionic, electronic contributions on conductivity respectively. Cells have been fabricated using copper as the anode and a conducting polymer as the cathode. Performances were evaluated using constant load discharge characteristics.
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